Volume 1 Issue 2
June  2022
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Qiang Luo, Zichao Wei, Hanyi Duan, Lei Jin, Rumasha N T Kankanamage, Seth Shuster, Steven L Suib, James F Rusling, Jie He. Templated synthesis of crystalline mesoporous CeO2 with organosilane-containing polymers: balancing porosity, crystallinity and catalytic activity[J]. Materials Futures, 2022, 1(2): 025302. doi: 10.1088/2752-5724/ac7605
Citation: Qiang Luo, Zichao Wei, Hanyi Duan, Lei Jin, Rumasha N T Kankanamage, Seth Shuster, Steven L Suib, James F Rusling, Jie He. Templated synthesis of crystalline mesoporous CeO2 with organosilane-containing polymers: balancing porosity, crystallinity and catalytic activity[J]. Materials Futures, 2022, 1(2): 025302. doi: 10.1088/2752-5724/ac7605
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Templated synthesis of crystalline mesoporous CeO2 with organosilane-containing polymers: balancing porosity, crystallinity and catalytic activity

© 2022 The Author(s). Published by IOP Publishing Ltd on behalf of the Songshan Lake Materials Laboratory
Materials Futures, Volume 1, Number 2
  • Received Date: 2022-04-26
  • Accepted Date: 2022-06-05
  • Publish Date: 2022-06-22
doi: 10.1088/2752-5724/ac7605

  • 1 Department of Chemistry, University of Connecticut, Storrs, CT 06269, United States of America

  • 2 Polymer Program, University of Connecticut, Storrs, CT 06269, United States of America

  • 3 Institute of Materials Science, University of Connecticut, Storrs, CT 06269, United States of America

  • 4 Department of Surgery and Neag Cancer Center, UConn Health, Farmington, CT 06232, United States of America

  • 5 School of Chemistry, National University of Ireland Galway, Galway, Ireland

Funds:

J H is grateful for the financial support from National Science Foundation (CEBT-1705566). The HR-TEM studies were performed using the facilities in the UConn Thermo Fisher Scientific Center for Advanced Microscopy and Materials Analysis (CAMMA). Low-magnification TEM and SEM images were obtained at the Biosciences Electron Microscopy Facility at the University of Connecticut. This work was also partially supported by the Green Emulsions Micelles and Surfactants (GEMS) Center of the University of Connecticut.

    Abstract

  • We report the synthesis of ordered mesoporous ceria (mCeO2) with highly crystallinity and thermal stability using hybrid polymer templates consisting of organosilanes. Those organosilane-containing polymers can convert into silica-like nanostructures that further serve as thermally stable and mechanically strong templates to prevent the collapse of mesoporous frameworks during thermal-induced crystallization. Using a simple evaporation-induced self-assembly process, control of the interaction between templates and metal precursors allows the co-self-assembly of polymer micelles and Ce3+ ions to form uniform porous structures. The porosity is well-retained after calcination up to 900◦C. After the thermal engineering at 700 ◦C for 12 h (mCeO2-700-12 h), mCeO2 still has a specific surface area of 96 m2 g-1 with a pore size of 14 nm. mCeO2 is demonstrated to be active for electrochemical oxidation of sulfite. mCeO2-700-12 h with a perfect balance of crystallinity and porosity shows the fastest intrinsic activity that is about 84 times more active than bulk CeO2 and 5 times more active than mCeO2 that has a lower crystallinity.

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    • References(84)
  • [1]
    Taguchi A and Schüth F 2005 Microporous Mesoporous Mater. 77 1–45
    [2]
    Rao Y and Antonelli D M 2009 J. Mater. Chem. 19 1937–44
    [3]
    Kuo C-H et al 2015 ACS Catal. 5 1693–9
    [4]
    Lu X, Ng Y H and Zhao C 2014 ChemSusChem 7 82–6
    [5]
    Luo W, Li Y, Dong J, Wei J, Xu J, Deng Y and Zhao D 2013 Angew. Chem., Int. Ed. 52 10505–10
    [6]
    Zu L, Zhang W, Qu L, Liu L, Li W, Yu A and Zhao D 2020 Adv. Energy Mater. 10 2002152
    [7]
    Xiong H, Zhou H, Sun G, Liu Z, Zhang L, Zhang L, Du F, Qiao Z A and Dai S 2020 Angew. Chem., Int. Ed. 59 11053–60
    [8]
    Brezesinski T, Wang J, Tolbert S H and Dunn B 2010 Nat. Mater. 9 146–51
    [9]
    Xu F, Jin S, Zhong H, Wu D, Yang X, Chen X, Wei H, Fu R and Jiang D 2015 Sci. Rep. 5 1–6
    [10]
    Joo J B, Dahl M, Li N, Zaera F and Yin Y 2013 Energy Environ. Sci. 6 2082–92
    [11]
    Tanaka M, Shima H, Yokoi T, Tatsumi T and Kondo J N 2011 Catal. Lett. 141 283–92
    [12]
    Ismail A A and Bahnemann D W 2011 J. Mater. Chem. 21 11686–707
    [13]
    Ismail A A, Bahnemann D W, Robben L, Yarovyi V and Wark M 2010 Chem. Mater. 22 108–16
    [14]
    Onozuka K, Kawakami Y, Imai H, Yokoi T, Tatsumi T and Kondo J 2012 J. Solid State Chem. 192 87–92
    [15]
    Hurum D C, Agrios A G, Gray K A, Rajh T and Thurnauer M C 2003 J. Phys. Chem. B 107 4545–9
    [16]
    Kawahara T, Konishi Y, Tada H, Tohge N, Nishii J and Ito S 2002 Angew. Chem., Int. Ed. 41 2811–3
    [17]
    Zhang L, Jin L, Liu B and He J 2019 Front. Chem. 7 22
    [18]
    Yue W and Zhou W 2008 Prog. Nat. Sci. 18 1329–38
    [19]
    Kondo J N and Domen K 2008 Chem. Mater. 20 835–47
    [20]
    Liu F, Liu C-L, Hu B, Kong W-P and Qi C-Z 2012 Appl. Surf. Sci. 258 7448–54
    [21]
    Zhang Z, Zuo F and Feng P 2010 J. Mater. Chem. 20 2206–12
    [22]
    Cop P, Kitano S, Niinuma K, Smarsly B and Kozuka H 2018 Nanoscale 10 7002–15
    [23]
    Zhang X, Yu X, Zhou B, Luo W, Jiang W, Jiang W, Shen Z and Wang L 2015 J. Am. Ceram. Soc. 98 1056–9
    [24]
    Liang C, Li Z and Dai S 2008 Angew. Chem., Int. Ed. 47 3696–717
    [25]
    Liu B et al 2015 Angew. Chem., Int. Ed. 54 9061–5
    [26]
    Lu A H and Schüth F 2006 Adv. Mater. 18 1793–805
    [27]
    Jiao F and Bruce P G 2007 Adv. Mater. 19 657–60
    [28]
    Deng X, Chen K and Tüysüz H 2017 Chem. Mater. 29 40–52
    [29]
    Cho H S and Ryoo R 2012 Microporous Mesoporous Mater. 151 107–12
    [30]
    Kruk M, Dufour B, Celer E B, Kowalewski T, Jaroniec M and Matyjaszewski K 2005 J. Phys. Chem. B 109 9216–25
    [31]
    Jin L, Liu B, Wu Y, Thanneeru S and He J 2017 ACS Appl. Mater. Interfaces 9 36837–48
    [32]
    Malgras V, Ataee-Esfahani H, Wang H, Jiang B, Li C, Wu K C W, Kim J H and Yamauchi Y 2016 Adv. Mater. 28 993–1010
    [33]
    Wang H, Jeong H Y, Imura M, Wang L, Radhakrishnan L, Fujita N, Castle T, Terasaki O and Yamauchi Y 2011 J. Am. Chem. Soc. 133 14526–9
    [34]
    Li W and Zhao D 2013 Chem. Commun. 49 943–6
    [35]
    Ren Y, Ma Z and Bruce P G 2012 Chem. Soc. Rev. 41 4909–27
    [36]
    Gu D and Schüth F 2014 Chem. Soc. Rev. 43 313–44
    [37]
    Yang P, Zhao D, Margolese D I, Chmelka B F and Stucky G D 1998 Nature 396 152–5
    [38]
    Yun H S, Miyazawa K C, Zhou H, Honma I and Kuwabara M 2001 Adv. Mater. 13 1377–80
    [39]
    Lee J, Christopher Orilall M, Warren S C, Kamperman M, Disalvo F J and Wiesner U 2008 Nat. Mater. 7 222–8
    [40]
    Zhang R, Tu B and Zhao D 2010 Chem. Eur. J. 16 9977–81
    [41]
    Wan Y and Zhao D 2007 Chem. Rev. 107 2821–60
    [42]
    Poyraz A S, Kuo C-H, Biswas S, King’ondu C K and Suib S L 2013 Nat. Commun. 4 2952
    [43]
    Li W et al 2011 Adv. Energy Mater. 1 382–6
    [44]
    Jin L et al 2020 Adv. Funct. Mater. 30 1909491
    [45]
    Jin L, Liu B, Louis M E, Li G and He J 2020 ACS Appl. Mater. Interfaces 12 9617–27
    [46]
    Hu M, Jin L, Su X, Bamonte S, Lu X, Gao P, Suib S L, Liu B and He J 2020 ChemCatChem 12 1476–82
    [47]
    Hu M, Jin L, Dang Y, Suib S L, He J and Liu B 2020 Front. Chem. 8 581512
    [48]
    Liu B, Jin L, Zheng H, Yao H, Wu Y, Lopes A and He J 2017 ACS Appl. Mater. Interfaces 9 1746–58
    [49]
    Liu B, Yao H, Daniels R A, Song W, Zheng H, Jin L, Suib S L and He J 2016 Nanoscale 8 5441–5
    [50]
    Liu B, Luo Z, Federico A, Song W, Suib S L and He J 2015 Chem. Mater. 27 6173–6
    [51]
    Li W, Kuo C-H, Kanyo I, Thanneeru S and He J 2014 Macromolecules 47 5932–41
    [52]
    Du J and Chen Y 2005 Macromol. Rapid Commun. 26 491–4
    [53]
    Montini T, Melchionna M, Monai M and Fornasiero P 2016 Chem. Rev. 116 5987–6041
    [54]
    Davó-Quiñonero A, Navlani-García M, Lozano-Castello D, Bueno-López A and Anderson J A 2016 ACS Catal. 6 1723–31
    [55]
    Vinodkumar T, Rao B G and Reddy B M 2015 Catal. Today 253 57–64
    [56]
    Mullins D and Zhang K 2002 Surf. Sci. 513 163–73
    [57]
    Durgasri D N, Vinodkumar T, Lin F, Alxneit I and Reddy B M 2014 Appl. Surf. Sci. 314 592–8
    [58]
    Li S et al 2017 Angew. Chem., Int. Ed. 56 10761–5
    [59]
    Ji P, Zhang J, Chen F and Anpo M 2008 J. Phys. Chem. C 112 17809–13
    [60]
    Roggenbuck J, Schäfer H, Tsoncheva T, Minchev C, Hanss J and Tiemann M 2007 Microporous Mesoporous Mater. 101 335–41
    [61]
    Laha S and Ryoo R 2003 Chem. Commun. 17 2138–9
    [62]
    Vickers S M, Gholami R, Smith K J and MacLachlan M J 2015 ACS Appl. Mater. Interfaces 7 11460–6
    [63]
    Kresge A C, Leonowicz M, Roth W J, Vartuli J and Beck J 1992 Nature 359 710–2
    [64]
    Pan J H, Zhao X and Lee W I 2011 Chem. Eng. J. 170 363–80
    [65]
    Bass J D, Grosso D, Boissiere C and Sanchez C 2008 J. Am. Chem. Soc. 130 7882–97
    [66]
    Crepaldi E L, Soler-Illia G J D A, Grosso D, Cagnol F, Ribot F and Sanchez C 2003 J. Am. Chem. Soc. 125 9770–86
    [67]
    Ansari S A, Khan M M, Ansari M O, Kalathil S, Lee J and Cho M H 2014 RSC Adv. 4 16782–91
    [68]
    Zhang J et al 2011 Adv. Energy Mater. 1 241–8
    [69]
    Mahoney L and Koodali R T 2014 Materials 7 2697–746
    [70]
    Amri F, Septiani N L W, Rezki M, Iqbal M, Yamauchi Y, Golberg D, Kaneti Y V and Yuliarto B 2021 J. Mater. Chem. B 9 1189–207
    [71]
    Dahal N, Ibarra I A and Humphrey S M 2012 J. Mater. Chem. 22 12675–81
    [72]
    Wang J, Li H, Li H, Zou C, Wang H and Li D 2014 ACS Appl. Mater. Interfaces 6 1623–31
    [73]
    Fan X, Wang T, Guo Y, Gong H, Xue H, Guo H, Gao B and He J 2017 Microporous Mesoporous Mater. 240 1–8
    [74]
    Hao C, Lv H, Mi C, Song Y and Ma J 2016 ACS Sustain. Chem. Eng. 4 746–56
    [75]
    Jin L, Liu C-H, Cintron D, Luo Q, Nieh M-P and He J 2021 Langmuir 37 9865–72
    [76]
    Kraffert K, Karg M, Schmack R, Clavel G, Boissiere C, Wirth T, Pinna N and Kraehnert R 2018 Adv. Mater. Interfaces 5 1800360
    [77]
    Schilling C, Hofmann A, Hess C and Ganduglia-Pirovano M V 2017 J. Phys. Chem. C 121 20834–49
    [78]
    Silva I D C, Sigoli F A and Mazali I O 2017 J. Phys. Chem. C 121 12928–35
    [79]
    Guhel Y, Ta M, Bernard J, Boudart B and Pesant J 2009 J. Raman Spectrosc. 40 401–4
    [80]
    O’brien J, Hinkley J, Donne S and Lindquist S-E 2010 Electrochim. Acta 55 573–91
    [81]
    Zelinsky A and Pirogov B Y 2017 Electrochim. Acta 231 371–8
    [82]
    Kim T W and Choi K-S 2014 Science 343 990–4
    [83]
    Randviir E P 2018 Electrochim. Acta 286 179–86
    [84]
    Sharma A, Bhattarai J K, Nigudkar S S, Pistorio S G, Demchenko A V and Stine K J 2016 J. Electroanal. Chem. 782 174–81
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