Volume 1 Issue 4
December  2022
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Bo Tong, Ziyu Song, Hao Wu, Xingxing Wang, Wenfang Feng, Zhibin Zhou, Heng Zhang. Ion transport and structural design of lithium-ion conductive solid polymer electrolytes: a perspective[J]. Materials Futures, 2022, 1(4): 042103. doi: 10.1088/2752-5724/ac9e6b
Citation: Bo Tong, Ziyu Song, Hao Wu, Xingxing Wang, Wenfang Feng, Zhibin Zhou, Heng Zhang. Ion transport and structural design of lithium-ion conductive solid polymer electrolytes: a perspective[J]. Materials Futures, 2022, 1(4): 042103. doi: 10.1088/2752-5724/ac9e6b
shu
Topical Review •
OPEN ACCESS

Ion transport and structural design of lithium-ion conductive solid polymer electrolytes: a perspective

© 2022 The Author(s). Published by IOP Publishing Ltd on behalf of the Songshan Lake Materials Laboratory
Materials Futures, Volume 1, Number 4
  • Received Date: 2022-09-30
  • Accepted Date: 2022-10-27
  • Publish Date: 2022-11-17
doi: 10.1088/2752-5724/ac9e6b

  • Key Laboratory of Material Chemistry for Energy Conversion and Storage, Huazhong University of Science and Technology, Wuhan 430074, Hubei, China

Funds:

The authors gratefully acknowledge the financial support provided by the Fundamental Research Funds for Central Universities, HUST (2020kfyXJJS095).

    Abstract

  • Solid polymer electrolytes (SPEs) possess several merits including no leakage, ease in process, and suppressing lithium dendrites growth. These features are beneficial for improving the cycle life and safety performance of rechargeable lithium metal batteries (LMBs), as compared to conventional non-aqueous liquid electrolytes. Particularly, the superior elasticity of polymeric material enables the employment of SPEs in building ultra-thin and flexible batteries, which could further expand the application scenarios of high-energy rechargeable LMBs. In this perspective, recent progresses on ion transport mechanism of SPEs and structural designs of electrolyte components (e.g. conductive lithium salts, polymer matrices) are scrutinized. In addition, key achievements in the field of single lithium-ion conductive SPEs are also outlined, aiming to provide the status quo in those SPEs with high selectivity in cationic transport. Finally, possible strategies for improving the performance of SPEs and their rechargeable LMBs are also discussed.

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