Volume 2 Issue 2
May  2023
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Yuan Liu, Xiaohui Rong, Fei Xie, Yaxiang Lu, Junmei Zhao, Liquan Chen, Yongsheng Hu. Unlocking the multi-electron transfer reaction in NASICON-type cathode materials[J]. Materials Futures, 2023, 2(2): 023502. doi: 10.1088/2752-5724/acc7bb
Citation: Yuan Liu, Xiaohui Rong, Fei Xie, Yaxiang Lu, Junmei Zhao, Liquan Chen, Yongsheng Hu. Unlocking the multi-electron transfer reaction in NASICON-type cathode materials[J]. Materials Futures, 2023, 2(2): 023502. doi: 10.1088/2752-5724/acc7bb
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Unlocking the multi-electron transfer reaction in NASICON-type cathode materials

© 2023 The Author(s). Published by IOP Publishing Ltd on behalf of the Songshan Lake Materials Laboratory
Materials Futures, Volume 2, Number 2
  • Received Date: 2023-01-27
  • Accepted Date: 2023-03-23
  • Publish Date: 2023-05-26
doi: 10.1088/2752-5724/acc7bb

  • 1 Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, People’s Republic of China

  • 2 College of Materials Science and Optoelectronic Technology, University of Chinese Academy of Sciences, Beijing 100049, People’s Republic of China

  • 3 Yangtze River Delta Physics Research Center Co. Ltd, Liyang 213300, People’s Republic of China

  • 4 Huairou Division, Institute of Physics, Chinese Academy of Sciences, Beijing 101400, People’s Republic of China

  • 5 CAS Key Laboratory of Green Process and Engineering, State Key Laboratory of Biochemical Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing, People’s Republic of China

Funds:

This work was supported by the National Key R&D Program of China (2022YFB3807800), National Natural Science Foundation (NSFC) of China (51725206, 52122214, 52002394, and 52072403), and Youth Innovation Promotion Association of the Chinese Academy of Sciences (2020006).

    Abstract
  • The growing concern about scarcity and large-scale applications of lithium resources has attracted efforts to realize cost-effective phosphate-based cathode materials for next-generation Na-ion batteries (NIBs). In previous work, a series of materials (such as Na4Fe3(PO4)2(P2O7), Na3VCr(PO4)3, Na4VMn(PO4)3, Na3MnTi(PO4)3, Na3MnZr(PO4)3, etc) with ∼120 mAh g−1 specific capacity and high operating potential has been proposed. However, the mass ratio of the total transition metal in the above compounds is only ∼22 wt%, which means that one-electron transfer for each transition metal shows a limited capacity (the mass ratio of Fe is 35.4 wt% in LiFePO4). Therefore, a multi-electron transfer reaction is necessary to catch up to or go beyond the electrochemical performance of LiFePO4. This review summarizes the reported NASICON-type and other phosphate-based cathode materials. On the basis of the aforementioned experimental results, we pinpoint the multi-electron behavior of transition metals and shed light on designing rules for developing high-capacity cathodes in NIBs.
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