Scheme 1.
Synthetic procedure for Ni5P4@NiSe2 heterostructure.
| Citation: |
Xue Han, Yanjie Liang, Lanling Zhao, Jun Wang, Qing Xia, Deyuan Li, Yao Liu, Zhaorui Zhou, Yuxin Long, Yebing Li, Yiming Zhang, Shulei Chou. A self-assembled nanoflower-like Ni5P4@NiSe2 heterostructure with hierarchical pores triggering high-efficiency electrocatalysis for Li-O2 batteries[J]. Materials Futures, 2022, 1(3): 035102. DOI: 10.1088/2752-5724/ac8170
|
Nowadays, the excessive consumption of fossil energy and serious environmental pollution has drawn our attention to developing energy storage devices with high energy densities [1-3]. It is evident that Li-O2 batteries hold great potential for next-generation battery systems, mainly due to their extra-high theoretical energy density (3500 Wh kg-1), which is related to the reversible redox reaction of 2Li+ + 2e- + O2 Li2O2 [4-6]. However, some problems still need to be solved, including low specific capacities, inferior rate capacity, high discharge/charge overpotentials and limited cycle life, which can be generated from the slow reaction kinetics towards oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) processes [7-9]. To overcome these obstacles, numerous researches have been carried out in recent years, in which the construction of efficient electrocatalysts can not only significantly improve the sluggish kinetics towards ORR/OER, but also limit the adverse parasitic reactions [10-12]. In other words, exploiting appropriate catalysts is crucial for improving the performance of Li-O2 batteries.
Among them, noble metals (Pd, Pt, Au) [13-15] are considered as ideal cathode catalysts to mitigate polarization and improve battery efficiency cycling performance, but the high price and scarcity restrain their large-scale application. Various alternatives have thus been extensively studied in Li-O2 batteries, such as carbon composites [16-18], alloys [19, 20], transition metal oxides [21-23], nitrides [24-26], sulfides [27-29], carbides [30-32] and phosphide [33-35], etc. Actually, it is well known that carbon materials are too sensitive to generate unwanted by-products, which could largely deteriorate the battery performance. According to recent literature reports, it is universally acknowledged that transition metal compounds are promising catalyst materials for electrical storage and electrocatalytic systems due to their excellent physicochemical properties, including tunable active centers and high catalytic activity. Among the transition metals, Ni element are moderately reserved and more affordable than Co element, and Ni-based compounds exhibit high catalytic activity when used as redox reaction sites [36, 37]. Most importantly, the presence of Ni3+ and Ni2+ redox couples could be easily obtained in the catalyst materials, realizing impressive electrocatalytic activities through promoting the formation/decomposition of Li2O2 [38]. Besides, Ni-based compounds have been intensively investigated and evaluated as cathode catalysts of Li-O2 batteries due to the environmental benignity, high chemical and thermal stability, as well as facile fabrication protocols [39-41]. As reported, transition metal selenides typically exhibit superior electrical conductivity due to their exceptional D-electron configuration and suitable energy position, which in turn leads to excellent electrocatalytic performance [42, 43]. Yoo’s [44] groups demonstrated that FeSe hollow spheroids delivered excellent stable cycle performance without significant changes in the overpotentials during cycling in Li-O2 batteries, and the SeOx on the surfaces of FeSe hollow spheroids contributed to facilitating ORR/OER bifunctional catalytic activities. Notably, transition metal phosphide surface polarization at the phosphorus terminus normally leads to negatively charged phosphorus centers, and the P sites with high electronegativity usually act as proton receptors, which facilitates the adsorption and desorption of intermediate species in oxygen electrocatalysis [35, 45]. For example, Du et al [46] successfully synthesized concave polyhedrons CoP with a high-index facet (211), which presented favorable electrocatalytic ability in Li-O2 batteries.
Since electrochemical reactions in Li-O2 batteries occur essentially at the three-phase interfaces, surface modifications, including defect engineering, heterogeneous atom doping and heterostructure construction, are proposed to effectively improve catalytic performance. In recent years, heterojunction engineering has received considerable research interests due to its unique physicochemical properties and practicality in designing unique electrocatalysts [47-50]. First, the built-in electric fields at the heterointerfaces could modulate the interfacial electronic structure and promote the reaction kinetics in the ORR/OER processes [51-53]. Besides, due to the high difference of electronegativity between Se (2.55) and P (2.19), the heterojunction interfaces could present two electrical regions of opposite charges [54, 55]. The strongly charged regions of Ni5P4 show the potential to optimize the chemisorption of reaction intermediates, and the electron-deficient regions of NiSe2 may act as active sites for continuity and accessibility via electron transfer, thus positively affecting the performance of Li-O2 batteries [56]. The conventional strategies for forming heterogeneous interfaces, however, are generally to employ the epitaxial growth methods in solution, and they cannot be widely applied in practical production due to the complicated processes [57, 58]. Therefore, it remains a challenge to effectively fabricate heterostructured catalysts with rich heterogeneous interfaces.
Herein, nanoflower-like Ni5P4@NiSe2 heterostructure was prepared and acted as a cathode catalyst for Li-O2 batteries, which delivered superior specific capacities and extended cycling life, compared with the Ni5P4 and NiSe2 counterparts. The improved catalytic activity of the nanoflower-like Ni5P4@NiSe2 heterostructure mainly stemmed from the built-in electric fields at the heterojunction interfaces, which effectively enhanced the electrical conductivity and thus improved the slow reaction kinetics in the charge and discharge processes. Moreover, the disordered atomic arrangement and the slight lattice distortion triggered by the Jahn-Teller effect at the heterogeneous interfaces could enable additional active sites to facilitate the regulation of the adsorption of oxygen-containing intermediates, which significantly improving the ORR/OER bifunctional catalytic activity. In addition, the constructed flower-like structure facilitated the construction of three-dimensional (3D) diffusion paths of Li+/O2 and provided sufficient room for the storage of discharge products. These results inspire promising strategies to develop new sufficiently stable electrocatalysts for Li-O2 batteries.
The precursor solution was obtained by dissolving 1 mmol Ni(NO3)2·6H2O, 8 mmol CH4N2O and 3 mmol NH4F into 30 ml of deionized water at room temperature with stirring for 20 min. Then, it was transferred into a 50 ml Teflon-lined stainless-steel autoclave and heated at 120 C for 24 h. After cooling down to room temperature, the as-prepared Ni(OH)2 was washed with deionized water and ethanol three times and dried at 50 C for 12 h in a vacuum oven.
Ni5P4@NiSe2 nanoflowers were prepared by simultaneous phosphorylation and selenization treatment. In brief, its fabrication was carried out in a tube furnace with as-prepared Ni(OH)2 precursor at the downstream and a mixture of Se powder and NaH2PO2 at the upstream at 350 C for 2.5 h with a heating rate of 2 C min-1 under an Ar atmosphere.
Field-emission scanning electron microscope (FESEM, Hitachi, S-4800, Japan) coupled with energy-dispersive x-ray spectroscope (EDX, Oxford Materials Analysis, UK) and high-resolution transmission electron microscope (HRTEM, JEOL-JEM 2100F, 200 kV, Japan) were used to investigate the morphologies and structures of the samples. The crystalline structures were recorded via x-ray diffraction (XRD, D/Max-IIIC, 36 kV and 20 mA, Japan). The Brunauer-Emmett-Teller (BET) specific surface areas and pore size distribution were examined by nitrogen adsorption/desorption isotherm (BET, Micromeritics ASAP2020). X-ray photoelectron spectroscopy (XPS, ESCALAB Xi+) was collected to characterize the surface chemical states, and all binding energies of the XPS spectra were adjusted by the carbon peak (C 1s) at around 284.8 eV. Exact two-phase ratio of Ni5P4@NiSe2 was obtained by inductively coupled plasma-atomic emission spectrometer (ICP-AES, Agilent-5110, USA).
To evaluate the electrochemical performance of the cathode catalysts for Li-O2 batteries, modified 2032 coin-type cells with holes on the cathode lid were assembled. To prepare the Ni5P4@NiSe2 cathodes, 40 wt % Ni5P4@NiSe2 powder, 40 wt % Ketjen black (KB) and 20 wt % poly-1,1,2,2-tetrafluoroethylene were mixed in 3 ml isopropanol under ultrasonic condition. The slurry was then uniformly dispersed on carbon papers and dried under vacuum at 120 C for 12 h. The Ni5P4 and NiSe2 cathodes were also prepared by the same method as above for comparison. The Li-O2 cells were assembled in a glovebox (Mbraun) with the prepared cathodes, Li sheet anodes and glass fiber separators with 1 M lithium bis(trifluoromethanesulfonyl)imide in triethylene glycol dimethyl ether (LTFSI/TEGDME) electrolyte. The electrochemical performance was measured by using a multi-channel cell test system (LAND CT 2001A). Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) were performed on an electrochemical workstation (CHI 660E, frequency region: 105-0.01 Hz, amplitude voltage: 10 mV).
Here, heterostructures can be described as the unique structures that consist of heterointerfaces formed by different materials through chemical or physical combinations. It is evident that the different work function () of Ni5P4 and NiSe2 are 4.97 and 6.88 eV, respectively [59, 60]. Meanwhile, NiSe2 presents semiconductor characteristics with a wide band gap energy (Eg) of about 1.96 eV, while Ni5P4 shows metallic properties due to the Femi level of Ni5P4 passed through the conduction band [61, 62]. Therefore, when they contacted with each other closely, a thermodynamic equilibrium was gained, and a space charge region would be formed, in which electrons were injected from NiSe2 to Ni5P4 [63]. And the built-in fields work mechanism of interfacial NiSe2 and Ni5P4 in equilibrium as shown in scheme 1. As a result, the surface of Ni5P4@NiSe2 heterostructure exhibits enriched electron density, and this implies a significant increase in electrical conductivity, which can further improve the electrocatalytic activity of the cell. The synthetic process of the Ni5P4@NiSe2 heterostructure was schematically illustrated in scheme 1, and its fabrication photograph was included in figure S1. First, Ni(NO3)2·6H2O, CH4N2O and NH4F were ultrasonically dispersed in deionized water under stirring, and the precursor of Ni(OH)2 was achieved after the hydrothermal treatment, evidenced by the data in figure S2. It was then further converted to Ni5P4@NiSe2 heterostructure by a simultaneous phosphorylation and selenization process at 350 C under the Ar atmosphere for 2.5 h. For comparison, Ni5P4 and NiSe2 nanoflowers were also obtained via the same fabrication route with phosphorylation or selenization, respectively.
It can be observed in figure S3 that the precursors were assembled in a nanoflower-like structure with an average diameter of 5
To further investigate the more detail microstructure of Ni5P4@NiSe2 heterostructure, the TEM image in figure 1(d) shows 3D hierarchical porous nanoflower-like morphology, which is well consistent with the SEM results. In figure 1(e), the lattice fringes with well-defined interfacial distances of 0.223 nm can be clearly described to the spacing of the (210) crystal planes of Ni5P4, meanwhile the lattice fringes of approximately 0.299 nm can be consistent with the (200) planes of NiSe2. Interestingly, figure 1(e) also depicts clear interfacial regions owing to the mismatch of the different phases, and the resulting strong electronic interaction between Ni5P4 and NiSe2 may lead to an increase in the active sites [43, 68, 69]. Figure 1(f) exhibits the corresponding selected area electron diffraction pattern of Ni5P4@NiSe2 heterostructure, which can be unambiguously indexed into (002), (201), (211), (302), (204) planes of the Ni5P4 and (200), (211) planes of the NiSe2, respectively, further demonstrating that Ni5P4@NiSe2 heterostructure was successfully synthesized.
The crystalline structure and phase of Ni5P4@NiSe2, Ni5P4 and NiSe2 were tested by XRD measurement. As depicted in figure 2(a), all diffraction peaks of Ni5P4@NiSe2 heterostructure correspond perfectly to hexagonal Ni5P4 (JCPDS. no 18-0883) and cubic NiSe2 (JCPDS. no 89-3058), which is identical to the HRTEM data. As we all know, electrocatalytic reactions in Li-O2 batteries generally mainly occur at the three-phase interfaces, and it is thus critical to analyze the surface elemental states of different samples [70]. XPS testing was used to study the bonding configuration and elemental composition of Ni5P4@NiSe2 and NiSe2. Figure 2(c) reveals the presence of C, O, Ni, P and Se elements on the as-prepared Ni5P4@NiSe2 heterostructure. Its Ni 2p spectrum in figure 2(d) shows two spin-orbit peaks, which are assigned to 2p3/2 and 2p1/2 signals. Moreover, the peaks can be respectively fitted to Ni3+ (855.9 and 873.9 eV), Ni2+ (852.7 and 869.8 eV) and the associated satellite (861.1 and 879.6 eV) peaks. Compared with those of pure NiSe2, the two-orbit doublets in the XPS spectrum of Ni5P4@NiSe2 heterostructure are slightly shifted to negative binding energies [55], which can be attributed to electronic structure changes caused by the interfacial charge redistribution of Ni5P4 and NiSe2. The high-resolution XPS spectrum of Se 3d (figure 2(e)) splits into two-component peaks at about 54.5 and 53.5 eV, related to Se 3d3/2 and Se 3d1/2 of Se2-. The Se 3d peak of Ni5P4@NiSe2 is normally accompanied by a 58.5 eV characteristic peak assigned to the Se-O bond, confirming that the surfaces of some Se species were oxidized to SeOx during the synthesis route [44, 66]. As can be seen in the high-resolution XPS spectrum of P 2p in figure 2(f), the peak of Ni5P4@NiSe2 heterostructure at 129.35 eV is ascribed to the Ni-P bond, and the peak at 133.7 eV demonstrates the presence of oxidation on the material surfaces [55, 71].
The electrocatalytic activity of Ni5P4@NiSe2 heterostructure was measured in Li-O2 batteries placed in a testing box purchased from NJZH (Shenzhen) Scientific Ltd, as displayed in figure S7. CV profiles of Ni5P4@NiSe2, Ni5P4, NiSe2 and pure KB cathodes within 2.35-4.5 V at 0.15 mV s-1 are depicted in figure 3(a). The Ni5P4@NiSe2 cathode exhibits the highest ORR/OER current densities, proving that it can significantly promote the electrocatalytic reaction kinetics. Specifically, the Ni5P4@NiSe2 cathode distinctly exhibits two negative peaks for OER, which are attributed to the different decomposition stages of discharge products [72-74]. It is proposed that the peak at 4.2 V is attributed to the delithiation process of Li2O2 (Li2O2 Li2-xO2 + x Li+ + x e-), while the lower peak at 3.78 V is ascribed to a further delithiation process (Li2-xO2 O2 + (2 - x) Li+ + (2 - x) e-) [7, 8].
The discharge/charge plots of Li-O2 batteries based on various cathodes were tested at the current density of 100 mA g-1 with the voltage range of 2.35-4.5 V versus Li+/Li. It is apparent in figure S8 that the initial discharge/charge specific capacities of carbon paper cathodes are negligible, which proves their contribution mainly comes from the active materials. As presented in figure 3(b), the Ni5P4@NiSe2 cathode exhibits the largest discharge/charge capacities of 19 090/19 031 mAh g-1 at 100 mA g-1, while those of Ni5P4, NiSe2 and pure KB cathodes are 16 831.5/14 153.5, 12 469.5/12 284 and 6689.75/5519.25 mAh g-1, respectively, with corresponding columbic efficiencies of 99.7%, 84.1%, 98.5% and 82.5%, illustrate superior eletrocatalytic activities of composite cathode. Moreover, the discharge/charge potentials of Ni5P4@NiSe2 cathode are about 2.74/4.20 V with the overpotentials of 0.20/1.26 V, respectively, which are significantly lower than those of Ni5P4 (0.25/1.42 V), NiSe2 (0.20/1.45 V) and pure KB (0.32/1.47 V) counterparts. Figure 3(c) shows the rate performance of Ni5P4@NiSe2, Ni5P4, NiSe2 and pure KB cathodes under different current densities with the cut-off capacity of 1000 mAh g-1. It can be seen that at current densities of 100, 200, 400, 800, 1000 and 100 mA g-1, the Ni5P4@NiSe2 cathode exhibits the largest/lowest terminal discharge/charge voltages. When the current density returns to 100 mA g-1, the terminal voltages remained almost unchanged compared to the initial values. Those differences in electrochemical properties demonstrate that the built-in electric fields with charge redistribution on heterostructure could improve the electrical conductivity of the cathode catalyst materials, thus effectively facilitating the formation and decomposition of discharge products [69]. In addition, the disordered atomic arrangement and the slight lattice distortion triggered by the Jahn-Teller effect at the heterogeneous interfaces could increase the reaction activity centers to boost electrocatalytic reactions [75-77]. It is thus concluded that the synergy of these two factors endowed the heterostructure cathodes excellent electrocatalytic performance. Figure 3(d) further shows the rate capability of Ni5P4@NiSe2 cathodes at different current densities under the voltage window of 2.35-4.5 V, and the pure KB cathode (figure S9) was also tested under the same conditions. As the current densities increased from 100 to 800 mA g-1, the ORR/OER overpotentials of Ni5P4@NiSe2 cathode increased to 0.20/1.45 V, and impressive discharge/charge specific capacities of 19 090/19 031, 18 026/17 802, 16 620/15 788 and 14 379/12 844 mAh g-1 at the current densities of 100, 200, 400 and 800 mA g-1 were also yielded, respectively. Moreover, the voltage platforms in the galvanostatic ORR/OER profiles of the Ni5P4@NiSe2 cathodes match well with the peaks of CV curves.
The cycle stability of different cathodes were evaluated with the fixed capacity of 1000 mAh g-1 at 200 mA g-1, as shown in figure 3(e). The terminal discharge/charge plots of Ni5P4@NiSe2 cathode was the most stable during cycling and can be effectively cycled up to 128 cycles, while those of Ni5P4, NiSe2 and pure KB cathodes dropped down quickly after 64, 28 and 20 cycles, respectively. Moreover, the excellent cycling performance of 202 cycles at a lower limiting capacity of 600 mAh g-1 with 100 mA g-1 was also included in figure 3(f). Table S1 shows a comparison of the battery performance in this work with previously reported similar counterparts. It can be well noticed that the Ni5P4@NiSe2 cathode exhibits long cycle stability and ultra-high discharge specific capacities, compared to those of transition metal phosphide and selenide cathodes. It is believed that the nanoflower-like Ni5P4@NiSe2 heterostructure with more free space and nanopores could construct a large amount of 3D channels for the fast Li+/O2 transport. Additionally, the built-in electric fields between Ni5P4 and NiSe2 can largely improve the slow redox kinetics of the cathode reactions, resulting in excellent electrochemical performance of Li-O2 batteries.
To explain the formation/decomposition mechanism and reason for the excellent electrocatalytic performance of Ni5P4@NiSe2 cathodes, ex-situ XRD, XPS and EIS at different stages during cycling were characterized. Figure 4(a) shows the XRD patterns of the Ni5P4@NiSe2 cathode at different stages, where two new diffraction peaks located at 32.9 and 35.0 after first discharging, indexed to (100) and (101) planes of Li2O2 (JCPDS. no 09-0355), respectively, and those of the fresh carbon paper cathode was also given in figure S10 for comparison. After 1st and 60th recharging, the diffraction peaks of Li2O2 fully disappeared, and almost no peaks of high crystalline by-products were traced. Meanwhile, EIS testing was carried out to measure the intrinsic kinetics characteristic at different discharge/charge stages. Typically, the EIS diagram contains two parts, the semicircle at high-frequency is associated with charge-transfer resistance (Rct), and the diagonal line at low-frequency is related to the ion diffusion properties. The date was fitted using the equivalent series circuit (inset of figure 4(b)). As shown in figure 4(b), the semicircles in the Ni5P4@NiSe2-based cell were greatly enlarged from 14.5 to 82.5 after first discharging, mainly due to the coverage and accumulation of insulating Li2O2 [18, 23]. Besides, it also shows that after first recharging and even after 100 cycles of prolonged cycling, the Rct of Ni5P4@NiSe2 cathode is close to its initial stage, demonstrating that the discharge products were almost decomposed. To further shed light on the composition of discharge products on Ni5P4@NiSe2 cathode, ex situ XPS experiments were studied, and the discharge/charge profiles with corresponding selected states are listed in figures 4(c)-(f). For discharged figure 4(e) relative to the initial stage, indicates that the main discharge products were Li2O2 and almost no by-products generation at this stage. After recharging (figure 4(f)), this peak no longer appeared, whereas the Se 3d3/2 and Se 3d1/2 peaks of the pristine cathode (figure 4(d)) can be detected at 54.5 and 53.5 eV. Those results further explain the ultra-long cycle life and stable cycling performance of Ni5P4@NiSe2 cathodes.
According to previous reports in the literature, the morphology of Li2O2 plays an essential role in affecting the subsequent charging process. Whether discharge products Li2O2 formed film- or disc-shaped was controlled by the adsorption energy of LiO2. The disc-shaped Li2O2 grew through the solution growth model due to the weak adsorption energy of the LiO2 intermediate, while the film-shaped Li2O2 was formed via a surface mechanism with strong adsorption energy of LiO2. As can be seen in figure 4(h), the surfaces of the Ni5P4@NiSe2 cathode were covered with film-like discharge products with great contact after being fully discharged distinct different from that at the fresh stage in figure 4(g). It is noteworthy that the evenly deposited film-like discharge products could facilitate the establishment of a good contact interface with the Ni5P4@NiSe2 cathode, which can make fully utilized of active centers and maximize the synergistic effect between Ni5P4, NiSe2 and the heterogeneous interfaces [7]. At the following recharging in figure 4(i), the film-like discharge products completely disappeared, showing almost the same nanoflower-like morphology as initial appearance, indicting the excellent reversibility of Li-O2 batteries with Ni5P4@NiSe2 cathodes.
|
Based on the above results, the superior electrocatalytic performance of Ni5P4@NiSe2 cathodes would be attributed to their unique architecture. The 3D nanoflower-like structure with self-assembled nanosheets not only promoted the diffusion of O2/Li+ throughout the cathode, but also provided sufficient active sites for storing the discharge products. Besides, the excellent electrical conductivity of the heterostructure can accelerate the charge transfer during the charge/discharge processes and enhance the electrochemical reaction kinetics [
|
(1) |
|
Second, O2.captured one electron and reacted with Li+ to generate LiO2 based on equation (2): O2∗+e−+ Li+→LiO2∗.
|
(2) |
|
Third, Li2O2 was formed by electrochemical reduction of LiO2 based on equation (3): LiO2∗+e−+ Li+→Li2O2∗.
|
(3) |
In summary, the nanoflower-like Ni5P4@NiSe2 heterostructure was successfully synthesized via hydrothermal method combining simultaneous phosphating/selenization treatment. The 3D hierarchical porous structure of Ni5P4@NiSe2 heterostructure can facilitate barrier-free Li+/O2 transport and provide sufficient specific surface area for the storage of discharge products. Moreover, the unique heterostructure shows a significant effect on the electron redistribution and disordered atomic arrangement, which can provide additional active sites to perfect the ORR/OER bifunctional catalytic activity. The Ni5P4@NiSe2 cathode delivered superior electrochemical performance, including an ultra-high discharge/charge specific capacity of 19 090/19 031 mAh g-1 and extended cycling life of 202 cycles at 100 mA g-1. The above results demonstrate that interfacial electron structure modulation by the construction of the heterogeneous structure with rational architecture design is a promising way of developing highly-efficient bifunctional electrode materials, which can also be expected to be employed in other energy catalytic applications.
Funding support is gratefully acknowledged by the National Natural Science Foundation of China (51971119, 52171141, U21A20311), the Natural Science Foundation of Shandong Province (ZR2020YQ32, ZR2020QB122), the China Postdoctoral Science Foundation (2020M672054), the Guangdong Basic and Applied Basic Research Foundation (2021A1515111124), the Young Scholars Program of Shandong University (2019WLJH21) and Project of Introducing Urgently Needed Talents in Key Supporting Regions of Shandong Province (2203-371703-04-01-786537).
Conflict of interest
The authors declare no conflict of interest.
Authors to whom any correspondence should be addressed.
| [1] |
Asadi M, et al 2018 A lithium-oxygen battery with a long cycle life in an air-like atmosphere Nature 555 502-6 DOI: 10.1038/nature25984
|
| [2] |
Liu Q C, Liu T, Liu D P, Li Z J, Zhang X B, Zhang Y 2016 A flexible and wearable lithium-oxygen battery with record energy density achieved by the interlaced architecture inspired by bamboo slips Adv. Mater. 28 8413-8 DOI: 10.1002/adma.201602800
|
| [3] |
Qiao Y, Wang Q F, Mu X W, Deng H, He P, Yu J H, Zhou H S 2019 Advanced hybrid electrolyte Li-O2 battery realized by dual superlyophobic membrane Joule 3 2986-3001 DOI: 10.1016/j.joule.2019.09.002
|
| [4] |
Xia Q, et al 2021 MnCo2S4-CoS1.097 heterostructure nanotubes as high efficiency cathode catalysts for stable and long-life lithium-oxygen batteries under high current conditions Adv. Sci. 8 2103302 DOI: 10.1002/advs.202103302
|
| [5] |
Ran Z Q, Shu C Z, Hou Z Q, Cao L J, Liang R X, Li J B, Hei P, Yang T S, Long J P 2020 Ni3Se2/NiSe2 heterostructure nanoforests as an efficient bifunctional electrocatalyst for high-capacity and long-life Li-O2 batteries J. Power Sources 468 228308 DOI: 10.1016/j.jpowsour.2020.228308
|
| [6] |
Hu A J, et al 2020 Heterostructured NiS2/ZnIn2S4 realizing toroid-like Li2O2 deposition in lithium-oxygen batteries with low-donor-number solvents ACS Nano 14 3490-9 DOI: 10.1021/acsnano.9b09646
|
| [7] |
Li D Y, et al 2022 CoS2 nanoparticles anchored on MoS2 nanorods as a superior bifunctional electrocatalyst boosting Li2O2 heteroepitaxial growth for rechargeable Li-O2 batteries Small 18 2105752 DOI: 10.1002/smll.202105752
|
| [8] |
Liu X M, Zhao L L, Xu H R, Huang Q S, Wang Y Q, Hou C X, Hou Y Y, Wang J, Dang F, Zhang J T 2020 Tunable cationic vacancies of cobalt oxides for efficient electrocatalysis in Li-O2 batteries Adv. Energy Mater. 10 2001415 DOI: 10.1002/aenm.202001415
|
| [9] |
Gu T H, Agyeman D A, Shin S J, Jin X, Lee J M, Kim H, Kang Y M, Hwang S J 2018 -MnO2 nanowire-anchored highly oxidized cluster as a catalyst for Li-O2 batteries: superior electrocatalytic activity and high functionality Angew. Chem., Int. Ed. Engl. 57 15984-9 DOI: 10.1002/anie.201809205
|
| [10] |
He B, Wang J, Fan Y Q, Jiang Y L, Zhai Y J, Wang Y, Huang Q S, Dang F, Zhang Z D, Wang N 2018 Mesoporous CoO/Co-N-C nanofibers as efficient cathode catalysts for Li-O2 batteries J. Mater. Chem. A 6 19075-84 DOI: 10.1039/C8TA07185C
|
| [11] |
Hou Y, Wang J, Hou C X, Fan Y, Zhai Y J, Li H Y, Dang F, Chou S L 2019 Oxygen vacancies promoting the electrocatalytic performance of CeO2 nanorods as cathode materials for Li-O2 batteries J. Mater. Chem. A 7 6552-61 DOI: 10.1039/C9TA00882A
|
| [12] |
Sennu P, Park H S, Park K U, Aravindan V, Nahm K S, Lee Y S 2017 Formation of NiCo2O4 rods over Co3O4 nanosheets as efficient catalyst for Li-O2 batteries and water splitting J. Catal. 349 175-82 DOI: 10.1016/j.jcat.2017.03.015
|
| [13] |
Liu X M, Huang Q S, Wang J, Zhao L L, Xu H R, Xia Q, Li D Y, Qian L, Wang H S, Zhang J 2021 In-situ deposition of Pd/Pd4S heterostructure on hollow carbon spheres as efficient electrocatalysts for rechargeable Li-O2 batteries Chin. Chem. Lett 32 2086-90 DOI: 10.1016/j.cclet.2020.11.003
|
| [14] |
Zhao W, Wang J, Yin R, Li B, Huang X S, Zhao L, Qian L 2020 Single-atom Pt supported on holey ultrathin g-C3N4 nanosheets as efficient catalyst for Li-O2 batteries J. Colloid Interface Sci. 564 28-36 DOI: 10.1016/j.jcis.2019.12.102
|
| [15] |
Wang P, Li C X, Dong S H, Ge X L, Zhang P, Miao X G, Zhang Z W, Wang C X, Yin L W 2019 One-step route synthesized Co2P/Ru/N-doped carbon nanotube hybrids as bifunctional electrocatalysts for high-performance Li-O2 batteries Small 15 1900001 DOI: 10.1002/smll.201900001
|
| [16] |
Wang J, Liu L L, Chou S L, Liu H K, Wang J Z 2017 A 3D porous nitrogen-doped carbon-nanofiber-supported palladium composite as an efficient catalytic cathode for lithium-oxygen batteries J. Mater. Chem. A 5 1462-71 DOI: 10.1039/C6TA07050G
|
| [17] |
Xu H R, Zhao L L, Liu X M, Li D Y, Xia Q, Cao X Y, Wang J, Zhang W B, Wang H S, Zhang J T 2021 CoMoP2 nanoparticles anchored on N, P doped carbon nanosheets for high-performance lithium-oxygen batteries FlatChem 25 100221 DOI: 10.1016/j.flatc.2020.100221
|
| [18] |
Zhai Y J, et al 2019 Highly efficient cobalt nanoparticles anchored porous N-doped carbon nanosheets electrocatalysts for Li-O2 batteries J. Catal. 377 534-42 DOI: 10.1016/j.jcat.2019.07.055
|
| [19] |
Leng L M, Li J, Zeng X Y, Song H Y, Shu T, Wang H S, Liao S L 2017 Enhancing the cyclability of Li-O2 batteries using PdM alloy nanoparticles anchored on nitrogen-doped reduced graphene as the cathode catalyst J. Power Sources 337 173-9 DOI: 10.1016/j.jpowsour.2016.10.089
|
| [20] |
Li K, Dong H Y, Wang Y W, Yin Y H, Yang S T 2020 Preparation of low-load Au-Pd alloy decorated carbon fibers binder-free cathode for Li-O2 battery J. Colloid Interface Sci. 579 448-54 DOI: 10.1016/j.jcis.2020.06.084
|
| [21] |
Yao W T, et al 2019 Tuning Li2O2 formation routes by facet engineering of MnO2 cathode catalysts J. Am. Chem. Soc. 141 12832-8 DOI: 10.1021/jacs.9b05992
|
| [22] |
Yang Z D, Chang Z W, Xu J J, Yang X Y, Zhang X B 2017 CeO2@NiCo2O4 nanowire arrays on carbon textiles as high performance cathode for Li-O2 batteries Sci. China Chem. 60 1540-5 DOI: 10.1007/s11426-017-9156-0
|
| [23] |
Zhao W, Li X M, Yin R, Qian L, Huang X S, Liu H, Zhang J X, Wang J, Ding T, Guo Z H 2018 Urchin-like NiO-NiCo2O4 heterostructure microsphere catalysts for enhanced rechargeable non-aqueous Li-O2 batteries Nanoscale 11 50-59 DOI: 10.1039/C8NR08457B
|
| [24] |
Guo Z Y, Wang F M, Li Z J, Yang Y, Tamirat A G, Qi H C, Han J S, Li W, Wang L, Feng S H 2018 Lithiophilic Co/Co4N nanoparticles embedded in hollow N-doped carbon nanocubes stabilizing lithium metal anodes for Li-air batteries J. Mater. Chem. A 6 22096-105 DOI: 10.1039/C8TA05013A
|
| [25] |
Xu S M, et al 2016 Toward lower overpotential through improved electron transport property: hierarchically porous CoN nanorods prepared by nitridation for lithium-oxygen batteries Nano Lett. 16 5902-8 DOI: 10.1021/acs.nanolett.6b02805
|
| [26] |
Dong S M, et al 2011 Molybdenum nitride based hybrid cathode for rechargeable lithium-O2 batteries Chem. Commun. 47 11291-3 DOI: 10.1039/c1cc14427h
|
| [27] |
Shombe G B, Khan M D, Choi J, Gupta R K, Opallo M, Revaprasadu N 2022 Tuning composition of CuCo2S4-NiCo2S4 solid solutions via solvent-less pyrolysis of molecular precursors for efficient supercapacitance and water splitting RSC Adv. 12 10675-85 DOI: 10.1039/D2RA00815G
|
| [28] |
Dou Y Y, Lian R Q, Zhang Y T, Zhao Y Y, Chen G, Wei Y J, Peng Z Q 2018 Co9S8@carbon porous nanocages derived from a metal-organic framework: a highly efficient bifunctional catalyst for aprotic Li-O2 batteries J. Mater. Chem. A 6 8595-603 DOI: 10.1039/C8TA01913D
|
| [29] |
Hou Z Q, Feng S, Hei P, Yang T S, Ran Z Q, Zheng R X, Liao X, Shu C Z, Long J P 2019 Morphology regulation of Li2O2 by flower-like ZnCo2S4 enabling high performance Li-O2 battery J. Power Sources 441 227168 DOI: 10.1016/j.jpowsour.2019.227168
|
| [30] |
Jiao W C, Su Q M, Ge J J, Dong S J, Wang D, Zhang M, Ding S K, Du G H, Xu B S 2021 Mo2C quantum dots decorated ultrathin carbon nanosheets self-assembled into nanoflowers toward highly catalytic cathodes for Li-O2 batteries Mater. Res. Bull. 133 111020 DOI: 10.1016/j.materresbull.2020.111020
|
| [31] |
Lai Y Q, Jiao Y F, Song J X, Zhang K, Li J, Zhang Z A 2018 Fe/Fe3C@graphitic carbon shell embedded in carbon nanotubes derived from Prussian blue as cathodes for Li-O2 batteries Mater. Chem. Front. 2 376-84 DOI: 10.1039/C7QM00503B
|
| [32] |
Liu C J, Qiu Z, Brant W R, Younesi R, Ma Y, Edstrm K, Gustafsson T, Zhu J 2018 A free standing Ru-TiC nanowire array/carbon textile cathode with enhanced stability for Li-O2 batteries J. Mater. Chem. A 6 23659-68 DOI: 10.1039/C7TA10930J
|
| [33] |
Huang H B, Luo S H, Liu C L, Yi T F, Zhai Y C 2018 High-surface-area and porous Co2P nanosheets as cost-effective cathode catalysts for Li-O2 batteries ACS Appl. Mater. Interfaces 10 21281-90 DOI: 10.1021/acsami.8b03736
|
| [34] |
Hou Z Q, Shu C Z, Hei P, Yang T S, Zheng R X, Ran Z Q, Long J P 2020 A 3D free-standing Co doped Ni2P nanowire oxygen electrode for stable and long-life lithium-oxygen batteries Nanoscale 12 6785-94 DOI: 10.1039/C9NR10793B
|
| [35] |
Ran Z Q, Shu C Z, Hou Z Q, Zhang W B, Yan Y, He M, Long J P 2021 Modulating electronic structure of honeycomb-like Ni2P/Ni12P5 heterostructure with phosphorus vacancies for highly efficient lithium-oxygen batteries Chem. Eng. J. 413 127404 DOI: 10.1016/j.cej.2020.127404
|
| [36] |
Liu G X, Zhang L, Wang S Q, Ding L X, Wang H H 2017 Hierarchical NiCo2O4nanosheets on carbon nanofiber films for high energy density and long-life Li-O2 batteries J. Mater. Chem. A 5 14530-6 DOI: 10.1039/C7TA03703A
|
| [37] |
Li J B, Shu C Z, Liu C H, Chen X F, Hu A J, Long J P 2020 Rationalizing the effect of oxygen vacancy on oxygen electrocatalysis in Li-O2 battery Small 16 2001812 DOI: 10.1002/smll.202001812
|
| [38] |
Wang L J, et al 2016 Facile synthesis of flower-like hierarchical NiCo2O4 microspheres as high-performance cathode materials for Li-O2 batteries RSC Adv. 6 98867-73 DOI: 10.1039/C6RA21414B
|
| [39] |
Li B, Zheng M B, Xue H G, Pang H 2016 High performance electrochemical capacitor materials focusing on nickel based materials Inorg. Chem. Front. 3 175-202 DOI: 10.1039/C5QI00187K
|
| [40] |
Zhang L Y, Shi D W, Liu T, Jaroniec M, Yu J G 2019 Nickel-based materials for supercapacitors Mater. Today 25 35-65 DOI: 10.1016/j.mattod.2018.11.002
|
| [41] |
Zhao C L, Lu Y X, Chen L Q, Hu Y S 2019 Ni-based cathode materials for Na-ion batteries Nano Res. 12 2018-30 DOI: 10.1007/s12274-019-2451-3
|
| [42] |
Wen X J, Ran Z Q, Zheng R X, Du D Y, Zhao C, Li R J, Xu H Y, Zeng T, Shu C Z 2022 NiSe2@NiO heterostructure with optimized electronic structure as efficient electrocatalyst for lithium-oxygen batteries J. Alloys Compd. 901 163703 DOI: 10.1016/j.jallcom.2022.163703
|
| [43] |
Yu J, Tian Y M, Lin Z W, Liu Q, Liu J Y, Chen R R, Zhang H S, Wang J 2021 NiSe2/Ni5P4 nanosheets on nitrogen-doped carbon nano-fibred skeleton for efficient overall water splitting Colloids Surf. A 614 126189 DOI: 10.1016/j.colsurfa.2021.126189
|
| [44] |
Yoo H, Lee G H, Kim D W 2021 FeSe hollow spheroids as electrocatalysts for high-rate Li-O2 battery cathodes J. Alloys Compd. 856 158269 DOI: 10.1016/j.jallcom.2020.158269
|
| [45] |
Yan Y T, Lin J H, Bao K, Xu T X, Qi J L, Cao J, Zhong Z X, Fei W D, Feng J C 2019 FeSe hollow spheroids as electrocatalysts for high-rate Li-O2 battery cathodes J. Colloid Interface Sci. 552 332-6 DOI: 10.1016/j.jcis.2019.05.064
|
| [46] |
Du D Y, Wang L, Zheng R X, Li M L, Ran Z Q, Ren L F, He M, Yan Y, Shu C Z 2021 Surface atomic modulation of CoP bifunctional catalyst for high performance Li-O2 battery enabled by high-index (2 1 1) facets J. Colloid Interface Sci. 601 114-23 DOI: 10.1016/j.jcis.2021.05.097
|
| [47] |
Yan Y, Ran Z Q, Zeng T, Wen X J, Xu H Y, Li R J, Zhao C, Shu C Z 2022 Interfacial electron redistribution of hydrangea-like NiO@Ni2P heterogeneous microspheres with dual-phase synergy for high-performance lithium-oxygen battery Small 18 2106707 DOI: 10.1002/smll.202106707
|
| [48] |
Veeramani V, Chen Y H, Wang H C, Hung T F, Chang W S, Wei D H, Hu S F, Liu R S 2018 CdSe/ZnS QD@CNT nanocomposite photocathode for improvement on charge overpotential in photoelectrochemical Li-O2 batteries Chem. Eng. J. 349 235-40 DOI: 10.1016/j.cej.2018.05.012
|
| [49] |
Zhu G J, Guo R, Luo W, Liu H K, Jiang W, Dou S X, Yang J 2021 Boron doping-induced interconnected assembly approach for mesoporous silicon oxycarbide architecture Natl Sci. Rev. 8 152 DOI: 10.1093/nsr/nwaa152
|
| [50] |
Wang T Z, Cao X J, Jiao L F 2021 Ni2P/NiMoP heterostructure as a bifunctional electrocatalyst for energy-saving hydrogen production eScience 1 69-74 DOI: 10.1016/j.esci.2021.09.002
|
| [51] |
Xu J J, Wang Z L, Xu D, Zhang L L, Zhang X B 2013 Tailoring deposition and morphology of discharge products towards high-rate and long-life lithium-oxygen batteries Nat. Commun. 4 2438 DOI: 10.1038/ncomms3438
|
| [52] |
Xu S M, Liang X, Liu X, Bai W L, Liu Y S, Cai Z P, Zhang Q, Zhao C, Wang K X, Chen J S 2020 Surface engineering donor and acceptor sites with enhanced charge transport for low-overpotential lithium-oxygen batteries Energy Storage Mater. 25 52-61 DOI: 10.1016/j.ensm.2019.10.032
|
| [53] |
Cheng H, Xie J, Cao G S, Lu Y H, Zheng D, Jin Y, Wang K Y, Zhao X B 2019 Realizing discrete growth of thin Li2O2 sheets on black phosphorus quantum dots-decorated -MnO2 catalyst for long-life lithium-oxygen cells Energy Storage Mater. 23 684-92 DOI: 10.1016/j.ensm.2019.02.028
|
| [54] |
Liu C C, Gong T, Zhang J, Zheng X R, Mao J, Liu H, Li Y, Hao Q Y 2020 Engineering Ni2P-NiSe2 heterostructure interface for highly efficient alkaline hydrogen evolution Appl. Catal. B 262 118245 DOI: 10.1016/j.apcatb.2019.118245
|
| [55] |
Yang J, Yang N, Xu Q, Pearlie L S, Zhang Y Z, Hong Y, Wang Q, Wang W J, Yan Q Y, Dong X C 2019 Bioinspired controlled synthesis of NiSe/Ni2P nanoparticles decorated 3D porous carbon for Li/Na ion batteries ACS Sustain. Chem. Eng. 7 13217-25 DOI: 10.1021/acssuschemeng.9b02478
|
| [56] |
Cui X H, Luo Y N, Zhou Y, Dong W H, Chen W 2021 Application of functionalized graphene in Li-O2 batteries Nanotechnology 32 132003 DOI: 10.1088/1361-6528/abd1a7
|
| [57] |
Yang Y, Zhang T, Wang X C, Chen L F, Wu N, Liu W, Lu H L, Xiao L, Fu L, Zhuang L 2016 Tuning the morphology and crystal structure of Li2O2: a graphene model electrode study for Li-O2 battery ACS Appl. Mater. Interfaces 8 21350-7 DOI: 10.1021/acsami.6b05660
|
| [58] |
Ye S F, Wang L F, Liu F F, Shi P C, Yu Y 2021 Integration of homogeneous and heterogeneous nucleation growth via 3D alloy framework for stable Na/K metal anode eScience 1 75-82 DOI: 10.1016/j.esci.2021.09.003
|
| [59] |
Ni S, Qu H N, Xu Z H, Zhu X Y, Xing H F, Wang L, Yu J M, Liu H Z, Chen C M, Yang L R 2021 Interfacial engineering of the NiSe2/FeSe2 p-p heterojunction for promoting oxygen evolution reaction and electrocatalytic urea oxidation Appl. Catal. B 299 120638 DOI: 10.1016/j.apcatb.2021.120638
|
| [60] |
Feng C J, Wang Y N, Lu Z W, Liang Q, Zhang Y Z, Li Z Y, Xu S 2022 Nanoflower Ni5P4 coupled with GCNQDs as Schottky junction photocatalyst for the efficient degradation of norfloxacin Sep. Purif. Technol. 282 120107 DOI: 10.1016/j.seppur.2021.120107
|
| [61] |
Liu X, Zhao Y X, Yang X F, Liu Q Q, Yu X H, Li Y Y, Tang H, Zhang T R 2020 Porous Ni5P4 as a promising cocatalyst for boosting the photocatalytic hydrogen evolution reaction performance Appl. Catal. B 275 119144 DOI: 10.1016/j.apcatb.2020.119144
|
| [62] |
Zhang X, Cheng Z W, Deng P H, Zhang L P, Hou Y 2021 NiSe2/Cd0.5Zn0.5S as a type-II heterojunction photocatalyst for enhanced photocatalytic hydrogen evolution Int. J. Hydrog. Energy 46 15389-97 DOI: 10.1016/j.ijhydene.2021.02.018
|
| [63] |
Li S Z, Zang W J, Liu X M, Pennycook S J, Kou Z K, Yang C H, Guan C, Wang J 2019 Heterojunction engineering of MoSe2/MoS2 with electronic modulation towards synergetic hydrogen evolution reaction and supercapacitance performance Chem. Eng. J. 359 1419-26 DOI: 10.1016/j.cej.2018.11.036
|
| [64] |
He B, et al 2020 Superassembly of porous Fetet(NiFe)octO frameworks with stable octahedron and multistage structure for superior lithium-oxygen batteries Adv. Energy Mater. 10 1904262 DOI: 10.1002/aenm.201904262
|
| [65] |
Li G Y, Li N, Peng S T, He B, Wang J, Du Y, Zhang W B, Han K, Dang F 2020 Highly efficient Nb2C MXene cathode catalyst with uniform O-terminated surface for lithium-oxygen batteries Adv. Energy Mater. 11 20022721 DOI: 10.1002/aenm.202002721
|
| [66] |
Zhang G L, Li G Y, Wang J, Tong H, Wang J C, Du Y, Sun S H, Dang F 2022 2D SnSe cathode catalyst featuring an efficient facet-dependent selective Li2O2 growth/decomposition for Li-oxygen batteries Adv. Energy Mater. 12 2103910 DOI: 10.1002/aenm.202103910
|
| [67] |
Zhao X J, et al 2021 Favorable anion adsorption/desorption of high rate NiSe2 nanosheets/hollow mesoporous carbon for battery-supercapacitor hybrid devices Nano Res. 14 2574-83 DOI: 10.1007/s12274-020-3257-z
|
| [68] |
Xie H, Chen M, Wu L 2019 Hierarchical nanostructured NiS/MoS2/C composite hollow spheres for high performance sodium-ion storage performance ACS Appl. Mater. Interfaces 11 41222-8 DOI: 10.1021/acsami.9b11078
|
| [69] |
Yang Y, Kang Y K, Zhao H H, Dai X P, Cui M, Luan X B, Zhang X, Nie F, Ren Z T, Song W Y 2019 An interfacial electron transfer on tetrahedral NiS2/NiSe2 heterocages with dualphase synergy for efficiently triggering the oxygen evolution reaction Small 16 1905083 DOI: 10.1002/smll.201905083
|
| [70] |
Xia Q, et al 2022 Recent advances in heterostructured cathodic electrocatalysts for non-aqueous Li-O2 batteries Chem. Sci. 13 2841-56 DOI: 10.1039/D1SC05781B
|
| [71] |
Zhou Q, et al 2022 Engineering in-plane nickel phosphide heterointerfaces with interfacial sp H-P hybridization for highly efficient and durable hydrogen evolution at 2 A cm-2 Small 18 2105642 DOI: 10.1002/smll.202105642
|
| [72] |
Huang H C, Cheng C J, Zhang G L, Guo L, Li G Y, Pan M, Dang F, Mai X M 2022 Surface phosphatization for a sawdustderived carbon catalyst as kinetics promoter and corrosion preventer in lithium-oxygen batteries Adv. Funct. Mater. 32 2111546 DOI: 10.1002/adfm.202111546
|
| [73] |
Wang Y, Li N, Hou C X, He B, Li J J, Dang F, Wang J, Fan Y Q 2020 Nanowires embedded porous TiO2@C nanocomposite anodes for enhanced stable lithium and sodium ion battery performance Ceram. Int. 46 9119-28 DOI: 10.1016/j.ceramint.2019.12.161
|
| [74] |
Dang C C, Wang Y, He B, Zhang W B, Dang F, Wang H C, Du Y 2020 Novel MoSi2 catalysts featuring surface activation as highly efficient cathode materials for long-life Li-O2 batteries J. Mater. Chem. A 8 259-67 DOI: 10.1039/C9TA10713D
|
| [75] |
Liang R X, Shu C Z, Hu A J, Li M L, Ran Z Q, Zheng R X, Long J P 2020 Interface engineering induced selenide lattice distortion boosting catalytic activity of heterogeneous CoSe2@NiSe2 for lithium-oxygen battery Chem. Eng. J. 393 124592 DOI: 10.1016/j.cej.2020.124592
|
| [76] |
Jin Y C, Liu Y, Song L, Yu J H, Li K R, Zhang M D, Wang J L 2022 Interfacial engineering in hollow NiS2/FeS2-NSGA heterostructures with efficient catalytic activity for advanced Li-CO2 battery Chem. Eng. J. 430 133029 DOI: 10.1016/j.cej.2021.133029
|
| [77] |
Wang W X, Xiong F Y, Zhu S H, Chen J H, Xie J, An Q Y 2022 Defect engineering in molybdenum-based electrode materials for energy storage eScience 2 278-94 DOI: 10.1016/j.esci.2022.04.005
|
| [78] |
Zhang F Z, Ma Y Y, Jiang M M, Luo W, Yang J P 2022 Boron heteroatom-doped silicon-carbon peanut-like composites enables long life lithium-ion batteries Rare Met. 41 1276-83 DOI: 10.1007/s12598-021-01741-0
|
| [79] |
Zhang F Z, Sherrell P C, Luo W, Chen J, Li W, Yang J P, Zhu M F 2021 Organic/inorganic hybrid fibers: controllable architectures for electrochemical energy applications Adv. Sci. 8 2102859 DOI: 10.1002/advs.202102859
|
| [80] |
Li D Y, Zhao L L, Xia Q, Wang J, Liu X M, Xu H R, Chou S L 2021 Activating MoS2 nanoflakes via sulfur defect engineering wrapped on CNTs for stable and efficient Li-O2 batteries Adv. Funct. Mater. 32 2108153 DOI: 10.1002/adfm.202108153
|
| [1] | Tianlong Liang, Yuantian Zheng, Qi'an Zhang, Ziyi Fang, Mingzhi Wu, Yang Liu, Qidong Ma, Jiazhen Zhou, Maryam Zulfiqar, Biyun Ren, Yanze Wang, Jingnan Zhang, Xiaoyu Weng, Dengfeng Peng. Downconversion mechanoluminescence from lanthanide codoped heterojunctions[J]. Materials Futures, 2025, 4(2): 025701. DOI: 10.1088/2752-5724/add7f3 |
| [2] | Meng Liu, Shoucong Ning, Dongdong Xiao, Yongzheng Zhang, Jiuhui Han, Chao Li, Anmin Nie, Xiang Zhang, Ao Zhang, Xiangrui Feng, Yujin Zhang, Weihua Wang, Zhen Lu, Haiyang Bai. Amorphous/crystalline heterostructured nanoporous high-entropy metallic glasses for efficient water splitting[J]. Materials Futures, 2025, 4(2): 025303. DOI: 10.1088/2752-5724/add415 |
| [3] | Yali Sun, Yun Li, Yang Zhou, Ting Cai, Yuxuan Chen, Chao Zou, Han Song, Shenghuang Lin, Shenghua Liu. MOF-MoS2 nanosheets doped PEDOT: PSS for organic electrochemical transistors in enhanced glucose sensing and machine learning-based concentration prediction[J]. Materials Futures, 2025, 4(2): 025302. DOI: 10.1088/2752-5724/adccdf |
| [4] | Xiaoming Lin, Jia Lin, Xiaomeng Lu, Xiaohong Tan, Hao Li, Wanxin Mai, Yuhong Luo, Yongbo Wu, Shuangqiang Chen, Chao Yang, Yong Wang. Vacancy-engineered LiMn2O4 embedded in dual-heteroatom-doped carbon via metal-organic framework-mediated synthesis towards longevous lithium ion battery[J]. Materials Futures, 2025, 4(2): 025101. DOI: 10.1088/2752-5724/ad9e08 |
| [5] | Yashu Guo, Zhijie Chen, Yinghui Lin, Gaihong Wang, Haoran Duan and Bing-Jie Ni. Heterojunction catalysts for urea oxidation reaction[J]. Materials Futures, 2025, 4(2): 022101. DOI: 10.1088/2752-5724/add60e |
| [6] | Xiang Xu, Yi Wang, Siyu Zhu, Qian Xu, Zulan Liu, Guotao Cheng, Dingpei Long, Lan Cheng, Fangyin Dai. Functionalized bio-spinning silk fiber scaffolds containing Mg2+ with osteoimmunomodulatory and osteogenesis abilities for critical-sized bone defect regeneration[J]. Materials Futures, 2025, 4(1): 015401. DOI: 10.1088/2752-5724/ad9e09 |
| [7] | Yingying Chen, Qiubao Lin, Haizhen Wang, Dehui Li. Interlayer excitons diffusion and transport in van der Waals heterostructures[J]. Materials Futures, 2025, 4(1): 012701. DOI: 10.1088/2752-5724/ad8cf2 |
| [8] | Amir Motaharinia, Jaroslaw W. Drelich, Safian Sharif, Ahmad Fauzi Ismail, Farid Naeimi, Alexandra Glover, Mahshid Ebrahiminejad, Hamid Reza Bakhsheshi-Rad. Overview of porous magnesium-based scaffolds: development, properties and biomedical applications[J]. Materials Futures, 2025, 4(1): 012401. DOI: 10.1088/2752-5724/ad9493 |
| [9] | Chunyan Zuo, Hengyuan Hu, Meisheng Han, Yejun Qiu, Guohua Tao. High performance energy-saving electrocatalysts for hydrogen evolution reaction: a minireview on the influence of structure and support[J]. Materials Futures, 2025, 4(1): 012101. DOI: 10.1088/2752-5724/ada99c |
| [10] | Jiayi Chen, Yi Yang, Jiaxin Chen, Haili Huang, Qia Shen, Shuai Shao, Yanran Zhang, Hao Yang, Xiaoxue Liu, Liang Liu, Shiyong Wang, Yaoyi Li, Canhua Liu, Hao Zheng, Dandan Guan, Jin-Feng Jia. One-dimensional magnetic chains in sub-monolayer CrTe2 grown on NbSe2[J]. Materials Futures. DOI: 10.1088/2752-5724/ade4e3 |
| 1. | Li, M., Xie, T., Chen, X. et al. Carbon-based composites decorated with NiCo alloy nanoparticles derived from metal-organic framework as supercapacitor electrodes. Materials Today Communications, 2025. DOI:10.1016/j.mtcomm.2025.111932 |
| 2. | Yang, J., Li, J., Xu, C. et al. Recent Advancements in Metal-Organic Frameworks-Derived Metal Phosphides as Anode for Lithium-Ion Batteries. ChemNanoMat, 2025, 11(2): e202400504. DOI:10.1002/cnma.202400504 |
| 3. | Ou, H., Li, P., Jiang, C. et al. Synergistic enhancement of Ni2P anode for high lithium/sodium storage by N, P, S triply-doping and soft template-assisted strategy. Journal of Colloid and Interface Science, 2025. DOI:10.1016/j.jcis.2024.08.182 |
| 4. | Feng, J., Li, Z., Zhao, L. et al. Built-in Electric Field and Te Charge Modulation in 2D Bi2Te3@Sb2Te3 Heterostructure Enable Ultralong Cycling for Lithium-Air Batteries. Advanced Functional Materials, 2025. DOI:10.1002/adfm.202504803 |
| 5. | Huang, M., Chen, Y., Zeng, W. et al. Enhancing lithium storage performance with silicon-based anodes: a theoretical study on transition metal-integrated SiOx/M@C (M = Fe, Co, Ni) heterostructures. Dalton Transactions, 2024, 53(37): 15481-15490. DOI:10.1039/d4dt02205j |
| 6. | Li, M., Yuan, M., Zheng, X. et al. Highly polar CoP/Co2P heterojunction composite as efficient cathode electrocatalyst for Li-air battery. Chinese Chemical Letters, 2024, 35(9): 109265. DOI:10.1016/j.cclet.2023.109265 |
| 7. | Ye, J., Xia, L., Li, H. et al. The Critical Analysis of Membranes toward Sustainable and Efficient Vanadium Redox Flow Batteries. Advanced Materials, 2024, 36(28): 2402090. DOI:10.1002/adma.202402090 |
| 8. | Huang, B., Zhang, Y., Zhong, H. et al. Strategy for the Preparation of ZnS/ZnO Composites Derived from Metal-Organic Frameworks toward Lithium Storage. Inorganic Chemistry, 2024, 63(26): 12281-12289. DOI:10.1021/acs.inorgchem.4c01680 |
| 9. | Tian, S.-L., Lin, L., Chang, L.-M. et al. Research progress of cathode catalyst for field-assisted Li-O2/CO2 battery. Journal of Energy Storage, 2024. DOI:10.1016/j.est.2024.111252 |
| 10. | Tian, S.-L., Li, M.-L., Chang, L.-M. et al. A highly reversible force-assisted Li − CO2 battery based on piezoelectric effect of Bi0.5Na0.5TiO3 nanorods. Journal of Colloid and Interface Science, 2024. DOI:10.1016/j.jcis.2023.11.090 |
| 11. | Guo, Y., Huang, M., Zhong, H. et al. Metal-organic frameworks-derived MCo2O4 (M = Zn, Ni, Cu) two-dimensional nanosheets as anodes materials to boost lithium storage. Journal of Colloid and Interface Science, 2023. DOI:10.1016/j.jcis.2023.07.099 |
| 12. | Hu, L., Zhong, P., Sang, X. et al. Integrating dual active sites on heterogeneous bimetallic selenide to facilitate hydrogen evolution and ethanol oxidation. Applied Surface Science, 2023. DOI:10.1016/j.apsusc.2023.157912 |
| 13. | Zhou, Z., Zhao, L., Wang, J. et al. Optimizing Eg Orbital Occupancy of Transition Metal Sulfides by Building Internal Electric Fields to Adjust the Adsorption of Oxygenated Intermediates for Li-O2 Batteries. Small, 2023, 19(41): 2302598. DOI:10.1002/smll.202302598 |
| 14. | Hu, L., Min, J., Zhong, P. et al. In-situ surface reconstructed NiOOH/Ni-ZnSe composite electrocatalysts with high activity toward oxygen evolution reaction in alkaline media. Inorganic Chemistry Communications, 2023. DOI:10.1016/j.inoche.2023.110970 |
| 15. | Han, X., Zhao, L., Wang, J. et al. Delocalized Electronic Engineering of Ni5P4 Nanoroses for Durable Li–O2 Batteries. Advanced Materials, 2023, 35(35): 2301897. DOI:10.1002/adma.202301897 |
| 16. | Meng, F., Xiong, X., He, S. et al. Post Nitrogen Electrocatalysis Era From Li–N2 Batteries to Zn–N2 Batteries. Advanced Energy Materials, 2023, 13(19): 2300269. DOI:10.1002/aenm.202300269 |
| 17. | Xie, Z., Lu, Z., Wang, J. et al. The Surface Electronic Structure Reconstruction of Co2.85Mn0.15O4 with High Active Sites for High-Efficient Lithium-Oxygen Batteries. ACS Sustainable Chemistry and Engineering, 2023, 11(17): 6698-6709. DOI:10.1021/acssuschemeng.3c00338 |
| 18. | Ye, J., Liu, J., Zheng, C. et al. Simple acid etched graphene oxide constructing high-performance sandwich structural hybrid membrane for redox flow battery. Sustainable Materials and Technologies, 2023. DOI:10.1016/j.susmat.2022.e00550 |
| 19. | Han, X., Zhao, L., Liang, Y. et al. Interfacial Electron Redistribution on Lattice-Matching NiS2/NiSe2 Homologous Heterocages with Dual-Phase Synergy to Tune the Formation Routes of Li2O2. Advanced Energy Materials, 2022, 12(47): 2202747. DOI:10.1002/aenm.202202747 |
Figures(5)
Copyright © 2021 Materials Futures Editorial Office
Supported by: Beijing Renhe Information Technology Co., Ltd. 
DownLoad:
